CSIRO Publishing blank image blank image blank image blank imageBooksblank image blank image blank image blank imageJournalsblank image blank image blank image blank imageAbout Usblank image blank image blank image blank imageShopping Cartblank image blank image blank image You are here: Journals > Environmental Chemistry   
Environmental Chemistry
Journal Banner
  Environmental problems - Chemical approaches
blank image Search
blank image blank image
blank image
  Advanced Search

Journal Home
About the Journal
Editorial Boards
Online Early
Current Issue
Just Accepted
All Issues
Virtual Issues
Special Issues
Research Fronts
Sample Issue
For Authors
General Information
Notice to Authors
Submit Article
Open Access
For Referees
Referee Guidelines
Review an Article
For Subscribers
Subscription Prices
Customer Service

blue arrow e-Alerts
blank image
Subscribe to our Email Alert or RSS feeds for the latest journal papers.

red arrow Connect with us
blank image
facebook twitter youtube


Article << Previous     |     Next >>   Contents Vol 3(6)

Mobile Voltammetric Laboratory for Ship-Board and Shore-Based Analyses of Dissolved Copper

Sarah Knight A D, Nicholas Morley B, Dónal Leech C, Rachel Cave A

A Department of Earth and Ocean Sciences, National University of Ireland, Galway, Ireland.
B ‘Burnside’, 1 Edward Street, Dunoon, Argyll PA23 7JF, Scotland, UK.
C Department of Chemistry, National University of Ireland, Galway, Ireland.
D Corresponding author. Email: sarah.knight@nuigalway.ie
PDF (307 KB) $25
 Export Citation

Environmental Context. Determining concentrations of dissolved copper in seawater is of interest, because copper (i) affects the health of aquatic biota, and (ii) has the potential to act as a water mass tracer, a marker which can be used to follow the movement of water in oceans. In situ analyses of copper and other trace metals in seawater have become increasingly popular, because they circumvent potential contamination problems associated with sample collection, storage, and transport to off-site analysis locations. This paper describes the assembly of a low-cost, mobile laboratory utilizing adsorptive cathodic stripping voltammetry (AdCSV) for the real-time determination of total dissolved copper in surface waters.

Abstract. The main advantages of using a mobile laboratory for the real-time analyses of copper in surface waters over classical discrete sampling include a reduction in the risk of sample contamination and significant savings in both time and money to the analyst. This paper outlines the development of a portable voltammetric laboratory, capable of deployment from ships or road vehicles, and an experimental method for the real time analysis of total dissolved copper in surface waters. It has been tested in estuarine and coastal waters to the west of Ireland and has proved suitable for the analysis of both fresh and marine waters. The system includes a trace metal-free sampling fish (for shipboard sampling), in-line filtration and UV-digestion units, and a voltammetric analyzer and electrode controlled by a portable PC. Analysis of samples is completed using adsorptive cathodic stripping voltammetry (AdCSV). Using this portable AdCSV laboratory, the high sample throughput – approximately three per hour with standard additions completed on every sample – means that for ship-board surveys good spatial coverage is possible without the need for time-consuming station stops. For van-based tidal surveys, the portable AdCSV laboratory is both straightforward and low in cost to deploy.

Keywords: dissolved copper — electrochemistry — in situ measurement — marine chemistry

Subscriber Login

Legal & Privacy | Contact Us | Help


© CSIRO 1996-2015