Environmental context. During flood events, the Fitzroy River is a major contributor to the loads of suspended sediment and nutrients to the southern Great Barrier Reef. The present geochemical and modelling study provides for the first time a quantitative estimate of the temporal variation in sediment sources over an entire flood hydrograph. Basaltic soils are substantially enriched in this flood event relative to their catchment abundance.

Abstract. Suspended sediment collected over a complete flood hydrograph in the Fitzroy River provided an insight into the origin and transport of sediment in this system. Strong temporal trends are evident in the proportions of catchment soil types estimated using a Bayesian mixing model in the fine (<10 μm) fraction of the suspended sediment. These temporal trends were also manifested in changes in mineralogy, major and trace element and Nd–Sr and C–N isotope geochemistry. Tertiary Basaltic soils were the most abundant catchment soil type transported in the flood event studied here, constituting 39% of the <10-μm sediment fraction, but varied between an estimated 20 and 50% of the suspended solids over the course of the flood event. The techniques used here allow quantification and comparison between flow and suspended sediment sources and are widely applicable to other river systems.