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Environmental problems - Chemical approaches
Environmental Chemistry

Environmental Chemistry

Volume 18 Number 7 2021

EN21118Analytical pitfalls when using inhibitors in specific nitrification assays

Guillaume Humbert 0000-0002-5071-1367, Mathieu Sebilo 0000-0002-3118-7416, Marion Chorin, Véronique Vaury and Anniet M. Laverman 0000-0003-1232-1189
pp. 295-299

Environmental context. Specific inhibitors of biological reactions in the nitrogen cycle can be used to determine the origin of reactive nitrogen species; these nitrogen species potentially degrade water quality or influence climate. However, inhibitors can potentially interfere with methods for the analysis of stable isotope ratios and concentrations of ammonium, nitrite and nitrate. The effect of this interference on several commonly used methods was investigated. These findings should help avoid the use of inappropriate analytical methods and improve data quality in studies of the nitrogen cycle.


Environmental context. The steroid hormone 17α-ethinylestradiol (EE2) has been established as a highly estrogenic substance, which potentially causes serious harm to environmental health. Rhamnolipids are a widely researched glycolipid used for the degradation of organic pollutants. Therefore, this study focused on the change of biodegradation of EE2 affected by rhamnolipids in sediment/water systems, showing increased and more rapid degradation.


Environmental context. The east coast of the Argentine Sea is frequently impacted by seasonal macroalgal blooms, resulting from anthropogenic activities such as the discharge of untreated wastewater. The use of these macroalgae for energy purposes through the anaerobic digestion process provides an opportunity to convert a biomass, currently considered as a waste, into a renewable energy source. Species specific differences and kinetics were studied and suggest this is a potentially useful novel energy source.

EN21103Speciation and mobility of antimony and arsenic in a highly contaminated freshwater system and the influence of extreme drought conditions

Steven Doherty 0000-0003-4474-1348, Matthew K. Tighe, Luke A. Milan, Leanne Lisle, Calvin Leech, Bernt Johannessen, Valerie Mitchell, Jessica Hamilton, Scott G. Johnston and Susan C. Wilson
pp. 321-333

Environmental context. Toxicity and mobility of antimony and arsenic in aqueous systems are largely determined by their speciation and redox chemistry. In a highly contaminated freshwater system, one antimony species (dissolved SbV) dominated, while dissolved arsenic was more responsive to environmental conditions. Arsenic (as AsV) increased significantly during a drought period; this increase in As mobility presents a threat for first flush events and water contamination in a changing climate.

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