Copper mediated in situ nucleophilic addition of polyalcohols to dicyanonitrosomethanide†
Mohd. R. Razali A B , Aron Urbatsch A , Boujemaa Moubaraki A , Keith S. Murray A , Glen B. Deacon A and Stuart R. Batten
A *
A School of Chemistry, 19 Rainforest Walk, Monash University, Vic. 3800, Australia.
B School of Chemical Sciences, Universiti Sains Malaysia, Penang, Malaysia.
Australian Journal of Chemistry 75(9) 725-731 https://doi.org/10.1071/CH21323
Submitted: 6 December 2021 Accepted: 7 February 2022 Published: 22 March 2022
© 2022 The Author(s) (or their employer(s)). Published by CSIRO Publishing. This is an open access article distributed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License (CC BY-NC-ND)
Abstract
The transition metal-promoted in situ nucleophilic addition of triethanolamine (teaH3) and N-methyldiethanolamine (mdeaH2) to the dicyanonitrosomethanide (dcnm) anion results in the formation of [Cu(hbnm)]·MeOH (1) and [Cu(mbnm)]·2MeCN (2), (hbnm = hydroxyethylaminobis(ethoxy(imino)methyl(cyano)nitrosomethanide) and mbnm = methylaminobis(ethoxy(imino)methyl(cyano)nitrosomethanide). Complexes 1 and 2 are coordination polymers, each containing the addition products of two alcohol arms of teaH3 and mdeaH2 to dcnm anions.
Keywords: coordination polymer, copper, crystal structure, dicyanonitrosomethanide, in situ reactions, magnetic properties, nucleophilic addition, small cyano anions.
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