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Article << Previous     |     Next >>   Contents Vol 39(12)

Kinetic Simulation of Polymerization Involving Termination by Reversible Chain Transfer

CHJ Johnson, G Moad, DH Solomon and TH Spurling

Australian Journal of Chemistry 39(12) 1943 - 1950
Published: 1986

Abstract

Numerical integration has been used as a means of simulating the title polymerization so that the variation of molecular weight and molecular weight distribution with reaction time (conversion) can be evaluated. The time/conversion dependence of the polydispersity (R) has been evaluated as a function of the relative magnitude of the rate constants associated with the initiation/termination equilibria . It is shown that the short term behaviour of R and the rate of approach to the value (R = 4/3) predicted by the steady state treatment have a marked dependence on the choice of rate constants.



Full text doi:10.1071/CH9861943

© CSIRO 1986

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