Conjoint Analysis of Kinetic and Equilibrium Data for Mechanistic Elucidation in Polynuclear Complexation Reactions, Exemplified by Metal(ii) Helicate Complex Formation

Sarah E. Clifford; Geoffrey A. Lawrance; Yorck-Michael Neuhold; Marcel Maeder

doi:10.1071/CH09316

RESEARCH ARTICLE

Previous Contents Vol 63(1)

Conjoint Analysis of Kinetic and Equilibrium Data for Mechanistic Elucidation in Polynuclear Complexation Reactions, Exemplified by Metal(ii) Helicate Complex Formation

Sarah E. Clifford ^A , Geoffrey A. Lawrance ^A , Yorck-Michael Neuhold ^A and Marcel Maeder ^A ^B

+ Author Affiliations

- Author Affiliations

^A Department of Chemistry, The University of Newcastle, Callaghan, NSW 2308, Australia.

^B Corresponding author. Email: marcel.maeder@newcastle.edu.au

Australian Journal of Chemistry 63(1) 141-144 https://doi.org/10.1071/CH09316
Submitted: 3 June 2009 Accepted: 3 September 2009 Published: 8 January 2010

Abstract

Combined kinetic and equilibrium studies of the complexation of the ligand N,N′-bis[2-(2-pyridyl)methyl]pyridine-2,6-dicarboxamide with copper(ii) and nickel(ii), examined conjointly employing advanced chemometric methods, provides elucidation of speciation and formation pathways in solution for complexes such as M₂L₂ and M₂L₃ helicates, respectively.

References

Conjoint Analysis of Kinetic and Equilibrium Data for Mechanistic Elucidation in Polynuclear Complexation Reactions, Exemplified by Metal(ii) Helicate Complex Formation

Abstract

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