Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Crystal Structure of a Heterometallic Luminophore: The RuII Complex of a Ferrocenyl-Terpyridine with a Flexible Linkage*

Young Hoon Lee A , Jong Won Shin B , Yusuke Sekimoto C , Shinya Hayami C , Jack Harrowfield D and Yang Kim E F
+ Author Affiliations
- Author Affiliations

A Department of Chemistry and EHSRC, University of Ulsan, Ulsan, 93 Daehak-ro, Nam-gu, Ulsan 44610, South Korea.

B Daegu-Gyeongbuk Branch, Korea Institute of Science and Technology Information, 90 Yutongdanji-ro, Buk-gu, Daegu 41515, South Korea.

C Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan.

D ISIS, Université de Strasbourg, 8 allée Gaspard Monge, 67083 Strasbourg, France.

E Department of Chemistry and Advanced Materials, Kosin University, 194, Wachi-Ro, Yeongdo-gu, Busan 49104, South Korea.

F Corresponding author. Email: ykim@kosin.ac.kr

Australian Journal of Chemistry 70(5) 632-636 https://doi.org/10.1071/CH16577
Submitted: 10 October 2016  Accepted: 23 November 2016   Published: 14 December 2016

Abstract

Crystal structure determination on the mixed ligand complex [Ru(tpy)(L1)](ClO4)2 (tpy = 2,2′:6′,2″-terpyridine; L1 = 4′-(ferrocenylmethylaminomethylphenyl)terpyridine) shows the ferrocenyl group to be located as remotely as possible from the RuII centre. This may explain the fact that emission from the RuII centre is detectable even at room temperature in solution.


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