Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Redox-State Dependent Spectroscopic Properties of Porous Organic Polymers Containing Furan, Thiophene, and Selenophene*

Carol Hua A , Stone Woo A , Aditya Rawal B , Floriana Tuna C , James M. Hook B , David Collison C and Deanna M. D’Alessandro A D
+ Author Affiliations
- Author Affiliations

A School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australia.

B NMR Facility, Mark Wainwright Analytical Centre, University of New South Wales, Sydney, NSW 2052, Australia.

C School of Chemistry, University of Manchester, Manchester M13 9PL, UK.

D Corresponding author. Email: deanna.dalessandro@sydney.edu.au

Australian Journal of Chemistry 70(11) 1227-1234 https://doi.org/10.1071/CH17335
Submitted: 15 June 2017  Accepted: 27 September 2017   Published: 25 October 2017

Abstract

A series of electroactive triarylamine porous organic polymers (POPs) with furan, thiophene, and selenophene (POP-O, POP-S, and POP-Se) linkers have been synthesised and their electronic and spectroscopic properties investigated as a function of redox state. Solid state NMR provided insight into the structural features of the POPs, while in situ solid state Vis-NIR and electron paramagnetic resonance spectroelectrochemistry showed that the distinct redox states in POP-S could be reversibly accessed. The development of redox-active porous organic polymers with heterocyclic linkers affords their potential application as stimuli responsive materials in gas storage, catalysis, and as electrochromic materials.


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