Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science

Electron impact studies. XXXI. Skeletal-rearrangement fragments in the mass spectra of anils

JH Bowie, RG Cooks, JW Fisher and T McL Spotswood

Australian Journal of Chemistry 21(8) 2021 - 2030
Published: 1968


Skeletal-rearrangement fragments are observed in the mass spectra of all anils derived from aromatic aldehydes. The rearrangement processes have been studied by high-resolution mass spectrometry and in certain cases by deuterium labelling. All processes are of the general type [ABC]+ → [AC]+ +B.

© CSIRO 1968

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