Complexes of Bis(cyclopentadienyl)titanium(III) chloride with some bidentate ligands

Abstract

Bis(cyclopentadienyl)titanium(111) chloride (cp₂TiCl) complexes with 1,l0-phenanthroline (phen), 2,2?-dipyridyl (dipy), o-phenylenediamine (phm), and α-picolylamine (picam) in anhydrous tetrahydrofuran to give cp₂TiCl,1.5L where L is the bidentate ligand. In air-free water all showed the conductivity of 1 : 1 electrolytes, but were insoluble in the common organic solvents.