Studies Directed Towards the Total Synthesis of Anticapsin and Related Compounds. III. A Ring-Fragmentation Route to the Anticapsin Skeleton
MJ Crossley and AW Stamford
Australian Journal of Chemistry
47(9) 1713 - 1726
Published: 1994
Abstract
The α-amino-5-oxo-7-oxabicyclo[4.1.0]heptane-2-propanoic acid framework of anticapsin and related compounds is generated by base-catalysed fragmentation of 2-amino-5,6-epoxy-1-hydroxybicyclo[2.2.2]octane-2-carboxylic acid derivatives in a retro-aldol-like reaction.
https://doi.org/10.1071/CH9941713
© CSIRO 1994
