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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Australian Journal of Chemistry

Australian Journal of Chemistry

Volume 75 Number 7 2022

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Reactions of [M(en)2]2+ and [M(3,7-diaza-nonane-1,9-diamine)]2+, M = Cu2+, Ni2+, with nitroethane and formaldehyde in basic solution to form (nitro, methyl)-substituted cyclic tetraamine cations, and reduction of the nitro-group(s) to form (amine, methyl)-substituted cyclic tetraamine cations are reviewed. This Review covers the preparations and properties of compounds of amine‐substituted cyclic amines formed via nitroalkane‐aldehyde condensations of metal‐ion amine compounds, and such compounds with the amine substituents chemically modified.

CH22076Studies on chitosan-g-polyethyleneimine copolymer as drug carriers for PolyI:C

Kai Zhang, Qian Sun, Peng Liu, Xiaoyu Bai, Xingtong Gao, Kai Liu, Aixiang Li 0000-0001-9271-5537, Zijian LYu and Qiuhong Li
pp. 467-476
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A chitosan-graft-polyethyleneimine copolymer (CS-g-PEI) was prepared by an N,N′-carbonyl diimidazole (CDI) coupling method as a drug carrier for PolyI:C and simulated antigen ovalbumin (OVA). Nanoparticles of CS-g-PEI-PolyI:C/OVA with good solution stability, coating effect, immune characteristics and suitable size were prepared through electrostatic self-assembly. CS-g-PEI protected PolyI:C from nuclease degradation and is a reliable drug carrier for the delivery of PolyI:C.

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Oil-in-water-in-oil (O/W/O) double Pickering emulsions were prepared using purified and modified attapulgite (ATP) and modified nano-Fe3O4 as stable particles and then used as templates to form ATP/P(MMA-BMA-St)/Fe3O4 composite porous resins. The experiment provides a simple, economic and environmentally friendly method for the preparation of inorganic–organic composite porous materials, which are expected to have great application potential in the field of oil treatment.

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