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Environmental problems - Chemical approaches
Environmental Chemistry

Environmental Chemistry

Volume 16 Number 5 2019

EN19135Origin of arsenolipids in sediments from Great Salt Lake

Ronald A. Glabonjat 0000-0003-3104-1940, Georg Raber, Kenneth B. Jensen, Florence Schubotz, Eric S. Boyd and Kevin A. Francesconi
pp. 303-311

Environmental context. Arsenic is a globally distributed element, occurring in various chemical forms with toxicities ranging from harmless to highly toxic. We examined sediment samples from Great Salt Lake, an extreme salt environment, and found a variety of organoarsenic species not previously recorded in nature. These new compounds are valuable pieces in the puzzle of how organisms detoxify arsenic, and in our understanding of the global arsenic cycle.


Environmental context. Organosulfates in the atmosphere are an indicator that particulate matter has formed from gases in the presence of anthropogenic pollution. By characterising organosulfates in atmospheric fine particulate matter from the Midwestern USA, we found that organosulfates account for a significant fraction of organic carbon and that they are associated with both plant-derived and anthropogenic gases. Our results demonstrate that anthropogenic pollution significantly influences atmospheric particle concentrations and composition.

EN18275Metal–organic complexes as a major sink for rare earth elements in soils

Petr S. Fedotov 0000-0003-0246-9905, Olga B. Rogova, Rustam Kh. Dzhenloda and Vasily K. Karandashev
pp. 323-332
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Environmental context. The role of rare earth elements in soil–plant systems remains unclear. We use continuous-flow extraction, designed to mimic natural conditions while minimising artefacts, to study in vitro chemical fractionation of rare earth elements in soil. The study reveals a predominant association of rare earth elements and metal-organic complexes independent of soil type and contamination, and thereby provides valuable insights into the behaviour of these elements in soil–plant systems.


Environmental context. Secondary organic aerosols account for a major fraction of atmospheric particulate matter, affecting both climate and human health. Organosulfates, abundant compounds in organic aerosols, are difficult to measure because of the lack of authentic standards. Here we quantify terpene-derived organosulfates in atmospheric particulate matter at a rural site in Germany and at the North China Plain using a combined target/non-target high-resolution mass spectrometry approach.


Environmental context. Antibiotic resistance by microorganisms in the natural environment poses a threat to ecosystems and public health. We report findings suggesting kaolinite can effectively inhibit the development of antibiotic resistance genes in microorganisms, and present a new understanding of the molecular mechanisms that promote the development of antibiotic resistance. These results are critical to mitigating environmental and public health risks resulting from the abuse of antibiotics.


Environmental context. Dissolved organic matter (DOM) is a highly diverse mixture of interacting compounds, which plays a key role in environmental processes in aquatic systems. The quality and functionality of DOM are measured using fluorescence spectroscopy, but established data analysis assumes linear behaviour, limiting the effectiveness of characterisation. We apply self-organising maps to fluorescence composition to improve the assessment of DOM quality and behaviour by visualising the interdependent nature of its components.

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