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Environmental problems - Chemical approaches
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Environmental Chemistry

Environmental Chemistry

Volume 17 Number 8 2020

EN19322Australian chlorofluorocarbon (CFC) emissions: 1960–2017

Paul J. Fraser 0000-0001-5951-6819, Bronwyn L. Dunse, Paul B. Krummel 0000-0002-4884-3678, L. Paul Steele, Nada Derek, Blagoj Mitrevski, Colin E. Allison, Zoë Loh, Alistair J. Manning, Alison Redington and Matthew Rigby
pp. 525-544

Environmental context. Chlorofluorocarbons (CFCs) are potent greenhouse and stratospheric ozone depleting trace gases. Their atmospheric concentrations are in decline, thanks to global production and consumption controls imposed by the Montreal Protocol. In recent years, the rates of decline of CFC atmospheric concentrations, especially for CFC-11 (CCl3F), are not as large as anticipated under the Protocol, resulting in renewed efforts to estimate CFC consumption and/or emissions to possibly identify new or poorly quantified sources.

EN20032Soil–air partitioning of volatile organic compounds into soils with high water content

Jeonghyeon Ahn, Guiying Rao, Mustafa Mamun and Eric P. Vejerano 0000-0002-6737-9057
pp. 545-557

Environmental context. Assessing environmental and human health impacts of chemical spills relies on information about how chemicals move across multiple environments. We measured volatile contaminants in the air above soil saturated with water to provide estimates of air concentrations of selected chemicals released to soil from an oil refinery in Texas during Hurricane Harvey. Estimated concentrations were below recommended exposure limits, even in a worst-case scenario.

EN20008Advanced PFAS precursor digestion methods for biosolids

Samuel Hutchinson 0000-0001-9429-4393, Tarsha Rieck and XiangLan Wu
pp. 558-567

Environmental context. The majority of biosolids produced in Australia from wastewater treatment processes are applied to agricultural land for beneficial use. We have demonstrated, through improvements to the analytical method, that levels of PFAS in biosolids are significantly higher than historically understood. The land application of biosolids could result in sensitive environments being exposed to PFAS at levels higher than previously anticipated.

EN19308Solar photocatalytic removal of arsenic from polluted water using carbon-modified titanium oxide nanoparticles supported on activated carbon

Radwan Kh. Alfarawati, Yasser A. Shaban 0000-0001-9236-4773, Adnan J. Turki, Yasar N. Kavil and Mousa I. Zobidi
pp. 568-578
Graphical Abstract Image

Environmental context. Contamination of water resources with arsenic is a serious environmental problem requiring efficient, viable and environmentally safe As removal processes. This study reports an arsenic remediation strategy using carbon modified titanium dioxide supported on activated carbon as a photocatalyst. The study highlights a practical process for efficient remediation of As-contaminated water under natural sunlight.

EN20078Temporal variation of trace elements, rare earth elements and Pb isotope ratios in sediment core from Kiel Bay, western Baltic Sea

Anna Maria Orani, Emilia Vassileva 0000-0002-7835-5640, Sabine Schmidt, Sylvain Berail and Julien P. G. Barre
pp. 579-593

Environmental context. Trace elements in coastal environments represent an environmental concern and their monitoring in sediment cores provides insight into their historical sources. A well-dated core from Kiel Bay, western Baltic Sea, provided trace element data, including lead, cadmium, rare earth elements, mercury and methyl mercury. Lead and mercury isotope ratios were useful for the apportionment of pollution sources, indicating that coal burning was a major contributor.

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