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Contents Vol 67(1)

Polymer Complexation by Hydrogen Bonding at the Interface

Shuguang Yang A C , Songmei Ma A , Chunyan Wang A , Jian Xu B and Meifang Zhu A
+ Author Affiliations
- Author Affiliations

A State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China.

B Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

C Corresponding author. Email: shgyang@dhu.edu.cn




Professor Shuguang Yang graduated from Wuhan University in 2002, and obtained his Ph.D. from the Institute of Chemistry, Chinese Academy of Sciences, in 2007. After one year as a research assistant in Peking University and two years as a research associate at the University of Akron, he joined Donghua University. His research activities include investigations of the hydrogen bonding dynamics of polymers, polymer interfacial complexation, polymer micellization, and interaction between polymers and colloidal particles.

Australian Journal of Chemistry 67(1) 11-21 https://doi.org/10.1071/CH13485
Submitted: 30 June 2013  Accepted: 3 October 2013   Published: 13 November 2013

Abstract

Polymer complexes can form in the bulk and at interfaces. Polymer complex formation in the bulk has been studied for a long time. The recently developed layer-by-layer assembly technique well realizes polymer complexation at interfaces. The layer-by-layer assembly of polymers based on Coulomb forces or hydrogen bonding is a repeated complexation process conducted at a surface. This paper reviews both single (once only) and repeatable interfacial complexation by hydrogen bonding, the available hydrogen bonding pairs for complexation, the thermodynamics and kinetics of complexation, and construction schemes.


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