One-Pot Synthesis of Core–Shell Structured Metal–Organic Coordination Polymer Microspheres with a Hierarchical Microporous–Mesoporous–Macroporous Structure
Yafang Zhou A , Yingxi Xu A , Jianyu Guo A C , Siyong Zhang A C and Yan Lu
B C
+ Author Affiliations
- Author Affiliations
A Department of Chemistry, Shanghai Normal University, Shanghai 200234, China.
B School of Engineering and Innovation, Shanghai Institute of Technology, Shanghai 201418, China.
C Corresponding authors. Email: gjychem@163.com; zsy515@shnu.edu.cn; luyanchem@163.com
Australian Journal of Chemistry 72(6) 450-459 https://doi.org/10.1071/CH18558
Submitted: 9 November 2018 Accepted: 13 February 2019 Published: 26 March 2019
Abstract
New core–shell structured metal–organic coordination polymer (CP) microspheres with a hierarchical microporous–mesoporous–macroporous structure are synthesized by a one-pot template-free method. The ligand L with a Schiff-base functional group is obtained by reacting 3-hydroxy-4-aminobenzoic acid with para-benzaldehyde. The coordination polymer microspheres (Zn-L-CP) are obtained by mixing the ligand L and zinc nitrate hexahydrate together under hydrothermal conditions. The resultant coordination polymer microspheres with a core–shell structure are characterized by FT-IR and solid state NMR spectroscopy, transmission and scanning electron microscopy, and nitrogen adsorption–desorption measurements. The obtained Zn-L-CP microspheres are proved to be effective heterogeneous catalysts for the deacetylation reaction with the merits of easy recycling and stability. The yield is 96 % when using methanol as solvent, and the yield can remain at 90 % after seven cycles.
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