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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Thermal Decomposition of Tertiary Butyl Chloride in the Presence of Sulphur Hexafluoride

RL Failes and VR Stimson

Australian Journal of Chemistry 15(3) 437 - 442
Published: 1962

Abstract

No acceleration of the gas-phase decomposition of tertiary butyl chloride at 284-309 °C occurs in the presence of sulphur hexafluoride. This behaviour contrasts with that of a variety of unimolecular decompositions probably occurring via triplet states where an extension of the simple theory of activation has been found necessary.

https://doi.org/10.1071/CH9620437

© CSIRO 1962

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