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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Gas-phase pyrolysis of isopropyl chloroformate

RL Johnson and VR Stimson

Australian Journal of Chemistry 35(4) 849 - 852
Published: 1982

Abstract

Homogeneous, molecular elimination of propene from isopropyl chloroformate takes place at 229-277ºC with rate

ke = 1013.94exp(-174000/8.314T) s-1

Rate comparisons indicate that a polar transition state is involved.

https://doi.org/10.1071/CH9820849

© CSIRO 1982

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