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Australian Journal of Chemistry Australian Journal of Chemistry Society
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RESEARCH ARTICLE

Complexation of Thallium(I) by 18-Crown-6, Dibenzo-18-crown-6 and Dicyclohexyl-18-crown-6 in Methanol and N,N-Dimethylformamide. Polarographic and MNDO Studies

E Lada, S Filipek and MK Kalinowski

Australian Journal of Chemistry 41(4) 437 - 441
Published: 1988

Abstract

The complexation of thallium(I) by 18-crown-6, dibenzo-18-crown-6 and dicyclohexyl-18-crown-6 (cis-anti-cis isomer) was studied in methanol and N,N- dimethylformamide by a polarographic technique. The equilibrium stability constants were compared with the electron density distributions, calculated by the MNDO method, at the oxygen atoms of the macrocycles.

https://doi.org/10.1071/CH9880437

© CSIRO 1988

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