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Australian Journal of Chemistry Australian Journal of Chemistry Society
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Australian Journal of Chemistry

Australian Journal of Chemistry

Volume 77 Number 1 2024

CH23146Recognising a beacon of teaching and learning leadership in Australian chemistry

Alex C. Bissember 0000-0001-5515-2878, Reyne Pullen 0000-0002-8617-1630 and Gwendolyn A. Lawrie 0000-0001-9839-6231

Graphic depicting chemistry academics working together as part of a community with a shared goal to implement changes in their own institution’s practices

The process of engaging chemistry academics across multiple institutions in conversations to establish consensus regarding measuring chemistry threshold learning outcomes (CTLOs) is complex. Brian Yates adopted a unique leadership approach by combining relational, distributed and collaborative leadership in initiating and supporting chemistry academic communities of practice (CoPs). (Image credit: Gwendolyn Lawrie.)

This article is part of the collection: Dedication to Brian Yates.

CH23153A novel ratiometric fluorescent sensor based on terpyridine derivatives for Zn2+ in aqueous solution

Qinghong Bai, Yangming Jiang, Enming Hu, Libin Lv 0000-0002-6132-2527, Chenghui Wang and Xin Xiao 0000-0001-6432-2875

Schematic representation of zinc ion binding to terpyridine probe producing solution color change from blue to yellow

We designed and synthesized a new fluorescent probe G based on 4-bromobenzaldehyde, CH3I and 4-vinylpyridine. Probe G formed a 1 : 1 complex with Zn2+ that produced a large fluorescence enhancement and a red shift of ~95 nm. Under ultraviolet light, on addition of Zn2+, the fluorescent color of probe G changed from blue to yellow. The tripyridine derivative probe G can quickly detect and identify zinc ions with high selectivity and a low detection limit in aqueous solution. (Image credit: Qinghong Bai.)


Schematic showing the complexation of 2-[(4-carboxyphenyl)methoxy]benzoic acid and 1,10-phenanthroline with various lanthanides and the resulting 2-D structure formed.

Four 2-D Ln-CPs [Ln = La (1), Pr (2), Sm (3), Eu (4)] based on mixed ligands, 2-[(4-carboxyphenyl)methoxy]benzoic acid (H2cob) and 1,10-phenanthroline (phen), were prepared and characterized. Complexes 3 and 4 show luminescence of the trivalent lanthanides. (Image credit: Lixin You.)


Chemical structures and reaction conditions for conversion of 3-arylmethyl sulfonyl imines to 3-arylcarbonyl analogues

A novel Co(OAc)2/NHPI-catalyzed oxidation of 3-arylmethyl sulfonyl imines to prepare 3-arylcarbonyl analogues has been realized. 3-Arylcarbonyl sulfonyl imines were comprehensively synthesized from benzyl substrates for the first time. The reactions proceeded in moderate to excellent yields. Mechanistic investigation suggests that alcohol compounds A are the key intermediates for the formation of products 2. (Image credit: Gan Haifeng.)


Photochromic inks and rewriting paper prepared with WO3-0.1Mo and WO3-0.1Cu.

The doping of WO3 with transition metal elements significantly optimised its photochromic properties. Mo changed the colour after UV irradiation and Cu increased the fading rate of WO3. Photochromic ink and photochromic rewriting paper were prepared using the obtained photochromic powders with a cycle life of more than 50 times. (Image credit: Xuhui Jin.)

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