|
Hydrated Lanthanoid Complexes of 5-(2′-Pyridyl)tetrazole Formed in the Presence of Dimethyl Sulfoxide *
Daniel
D'Alessio A,
Louise E.
Karagiannidis A B,
Brian W.
Skelton C,
Massimiliano
Massi A and
Mark I.
Ogden A D
A
Department of Chemistry, Curtin University, GPO Box U 1987, Perth, WA 6845, Australia.
B
Chemistry, University of Southampton, Southampton, SO17 1BJ, UK.
C
Centre for Microscopy, Characterisation and Analysis, M313, University of Western Australia, Perth, WA 6009, Australia.
D
Corresponding author. Email: m.ogden@curtin.edu.au
Australian Journal of Chemistry
65(7)
819-822 http://dx.doi.org/10.1071/CH12031
Submitted: 19 January 2012 Accepted: 18 February 2012 Published:
2
April
2012
|  |
|
|
Abstract
Reaction of DMSO solvates of lanthanoid nitrates or perchlorates with 5-(2′-pyridyl)tetrazole (pytz) and triethylamine in organic solvents resulted in the unexpected crystallization of hydrates, rather than DMSO solvates. This was confirmed by the structural characterization of [Eu(pytz)3(H2O)3]. Decreasing the metal:ligand ratio in the reaction mixture resulted in the crystallization of a complex salt formulated as [Y(pytz)2(H2O)4](pytz)·(Hpytz)·4H2O; once again DMSO was absent from the product. Interestingly, the omission of base from one reaction resulted in the serendipitous crystallization of Hpytz in a zwitterionic form, unlike the neutral ligand structure reported previously. 
|
References
[1]
R. J. Herr, Bioorg. Med. Chem. 2002, 10, 3379.
| CrossRef | CAS | 
[2]
S. Stagni, S. Colella, A. Palazzi, G. Valenti, S. Zacchini, F. Paolucci, M. Marcaccio, R. Q. Albuquerque, L. De Cola, Inorg. Chem. 2008, 47, 10509.
| CrossRef | CAS |
[3]
M. V. Werrett, D. Chartrand, J. D. Gale, G. S. Hanan, J. G. MacLellan, M. Massi, S. Muzzioli, P. Raiteri, B. W. Skelton, M. Silberstein, S. Stagni, Inorg. Chem. 2011, 50, 1229.
| CrossRef | CAS |
[4]
H. Zhao, Z. R. Qu, H. Y. Ye, R. G. Xiong, Chem. Soc. Rev. 2008, 37, 84.
| CrossRef |
[5]
P. C. Andrews, T. Beck, B. H. Fraser, P. C. Junk, M. Massi, Polyhedron 2007, 26, 5406.
| CrossRef | CAS |
[6]
P. C. Andrews, P. C. Junk, M. Massi, M. Silberstein, Chem. Commun. (Camb.) 2006, 3317.
| CrossRef | CAS |
[7]
Y.-S. Zhou, D.-H. Xu, L.-J. Zhang, Chem. Res. Chin. Univ. 2010, 26, 866.
| CAS |
[8]
A. Facchetti, A. Abbotto, L. Beverina, S. Bradamante, P. Mariani, C. L. Stern, T. J. Marks, A. Vacca, G. A. Pagani, Chem. Commun. (Camb.) 2004, 1770.
| CrossRef | CAS |
[9]
C. R. Driscoll, B. L. Reid, M. J. McIldowie, S. Muzzioli, G. L. Nealon, B. W. Skelton, S. Stagni, D. H. Brown, M. Massi, M. I. Ogden, Chem. Commun. (Camb.) 2011, 47, 3876.
| CrossRef | CAS |
[10]
P. C. Andrews, T. Beck, B. H. Fraser, P. C. Junk, M. Massi, B. Moubaraki, K. S. Murray, M. Silberstein, Polyhedron 2009, 28, 2123.
| CrossRef | CAS |
[11]
P. C. Andrews, G. B. Deacon, R. Frank, B. H. Fraser, P. C. Junk, J. G. MacLellan, M. Massi, B. Moubaraki, K. S. Murray, M. Silberstein, Eur. J. Inorg. Chem. 2009, 744.
| CrossRef | CAS |
[12]
A. Dossing, Eur. J. Inorg. Chem. 2005, 1425.
| CrossRef | CAS |
[13]
L. I. Semenova, B. W. Skelton, A. H. White, Aust. J. Chem. 1996, 49, 997.
| CrossRef | CAS |
[14]
E. J. Chan, B. G. Cox, J. M. Harrowfield, M. I. Ogden, B. W. Skelton, A. H. White, Inorg. Chim. Acta 2004, 357, 2365.
| CrossRef | CAS |
[15]
Z. Asfari, J. M. Harrowfield, M. I. Ogden, J. Vicens, A. H. White, Angew. Chem. Int. Edit. 1991, 30, 854.
| CrossRef |
[16]
S. Fleming, C. D. Gutsche, J. M. Harrowfield, M. I. Ogden, B. W. Skelton, D. F. Stewart, A. H. White, Dalton Trans. 2003, 3319.
| CrossRef | CAS |
[17]
J. M. Harrowfield, M. I. Ogden, A. H. White, Aust. J. Chem. 1991, 44, 1237.
| CrossRef | CAS |
[18]
I. Sanchez-Lombardo, C. M. Andolina, J. R. Morrow, A. K. Yatsimirsky, Dalton Trans. 2010, 39, 864.
| CrossRef | CAS |
[19]
P. Di Bernardo, A. Melchior, M. Tolazzi, P. L. Zanonato, Coord. Chem. Rev. 2012, 256, 328.
| CrossRef | CAS |
[20]
I. Sanchez-Lombardo, A. K. Yatsimirsky, Inorg. Chem. 2008, 47, 2514.
| CrossRef | CAS |
[21]
F. Tanaka, Y. Kawasaki, S. Yamashita, J. Chem. Soc., Faraday Trans. I 1988, 84, 1083.
| CrossRef | CAS |
[22]
A. T. Rizk, C. A. Kilner, M. A. Halcrow, CrystEngComm 2005, 7, 359.
| CrossRef | CAS |
[23]
V. N. Krishnamurthy, S. Soundararajan, J. Inorg. Nucl. Chem. 1967, 29, 517.
| CrossRef | CAS |
[24]
G. M. Sheldrick, Acta Crystallogr. 2008, A64, 112.
| CAS |
|
|
 |
Subscriber Login |
 |
|
e-Alerts
Connect with us
