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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Organomercury compounds. XI. Some coordination derivatives of bispentafluorophenylmercury

AJ Canty and GB Deacon

Australian Journal of Chemistry 24(3) 489 - 499
Published: 1971

Abstract

The complexes (C6F5)2HgL (L = 4,4?-dimethyl-2,2?-bipyridyl, 2,2?- biquinolyl, 2,2?:6?,2?-terpyridyl, 2,4,7,9,-tetramethyl-1,10- phenanthroline, ethylenediamine, o-phenylenediamine, diphenylamine, pyridine, 4-cyanopyridine, triphenylphosphine, triphenylphosphine oxide, or 1,2-bisdiphenylarsinoethane), (C6F5)2HgL2 (L = di-2- pyridylamine), and [(C6F5)2Hg]2L (L = bisdiphenylphosphinomethane or bisdiphenyl-arsinomethane) have been prepared, and their constitution, solution stabilities, and structures studied, together with those of the known complexes (C6F5)2HgL (L = 2,2?- bipyridyl, 1,10-phenanthroline, or 1,2-bisdiphenylphosphinoethane). Coordination of triphenylarsine oxide to bispentafluorophenylmercury in solution has also been detected, but the complex could not be isolated.

https://doi.org/10.1071/CH9710489

© CSIRO 1971

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