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Article << Previous     |         Contents Vol 36(2)

Synthesis of ketones and methanols containing pyridinyl and N-methylimidazolyl groups

AJ Canty, EE George and CV Lee

Australian Journal of Chemistry 36(2) 415 - 418
Published: 1983

Abstract

N-Methylimidazolyllithium reacts with N-methylimidazole-2-carbaldehyde to form bis(N-methylimidazol-2-yl)methanol, and with the esters ethyl N-methylimidazole-2-carboxylate and ethyl pyridine-2-carboxylate to give bis(N-methylimidazol-2-yl)methanone,(mim)2CO, and (N-methyl- imidazol-2-yl)(pyridin-2-yl)methanone, (Py)(mim)CO, respectively. The ketones react with N-methylimidazolyllithium to give tris(N-methylimidazol-2-yl)methanol, (mim)3 COH, and bis(N- methylimidazol-2-yl)(pyridin-2-yl)methanol (Py)(mim)2 COH, respectively.



Full text doi:10.1071/CH9830415

© CSIRO 1983

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