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RESEARCH ARTICLE
Contents Vol 71(8)

Efficient Hydrolytic Breakage of β-1,4-Glycosidic Bond Catalyzed by a Difunctional Magnetic Nanocatalyst

Ren-Qiang Yang A , Ni Zhang A , Xiang-Guang Meng A B , Xiao-Hong Liao A , Lu Li A and Hong-Jin Song A
+ Author Affiliations
- Author Affiliations

A Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China.

B Corresponding author. Email: mengxgchem@163.com

Australian Journal of Chemistry 71(8) 559-565 https://doi.org/10.1071/CH18138
Submitted: 5 April 2018  Accepted: 5 July 2018   Published: 14 August 2018

Abstract

A novel difunctional magnetic nanocatalyst (DMNC) was prepared and used to catalyse the hydrolytic breakage of β-1,4-glycosidic bonds. The functional nanoparticle displayed excellent catalytic activity for hydrolysis of cellobiose to glucose under moderate conditions. The conversion of cellobiose and yield of glucose could reach 95.3 and 91.1 %, respectively, for a reaction time of 6 h at pH 4.0 and 130°C. DMNC was also an efficient catalyst for the hydrolysis of cellulose: 53.9 % microcrystalline cellulose was hydrolyzed, and 45.7 % reducing sugar was obtained at pH 4.0 and 130°C after 10 h. The magnetic catalyst could be recycled and reused five times without significant loss of catalytic activity.


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