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RESEARCH ARTICLE
Contents Vol 71(12)

Adsorption of PtCl62− from Hydrochloric Acid Solution by Chemically Modified Lignin Based on Rice Straw

Baoping Zhang A B C , Bowen Shen A B , Meichen Guo A B and Yun Liu A B
+ Author Affiliations
- Author Affiliations

A The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, Hubei 430081, China.

B Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, Hubei 430081, China.

C Corresponding author. Email: zhangbaoping@wust.edu.cn

Australian Journal of Chemistry 71(12) 931-938 https://doi.org/10.1071/CH18282
Submitted: 7 June 2018  Accepted: 19 September 2018   Published: 15 October 2018

Abstract

A novel adsorbent with the properties of selective adsorption based on rice straw was used to adsorb PtCl62− from hydrochloric acid solution by batch sorption. Many influencing factors for PtCl62− adsorption, such as initial concentration of PtCl62−, adsorption time, and concentration of hydrochloric acid, were optimized. The results suggested that the saturation adsorption capacity of PtCl62− was 218.8 mg g−1 and the equilibrium adsorption time was 120 min. The adsorbent had excellent selectivity on PtCl62− when the concentration of hydrochloric acid was lower than 0.5 mol L−1. The adsorption fitted well with the Langmuir isotherm model and pseudo-second-order kinetics model. The adsorption mechanism was investigated by FT-IR and X-ray photoelectron spectroscopy analyses and it indicated that PtIV was reduced to PtII by hydroxy groups and then coordinated with N through ion exchange between Cl− and PtCl42−.


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