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RESEARCH ARTICLE
Contents Vol 73(1)

Assembly of Three Lanthanide Coordination Polymers from 2-(4-Carboxybenzyloxy) Benzoic Acid Ligand: Synthesis, Structure, and Fluorescent Properties

Shu-Ju Wang A , Yi-Hui Jiang A , Han-Lin Wu A , Li-Xin You https://orcid.org/0000-0003-1017-3901 A B , Gang Xiong A , Fu Ding A and Ya-Guang Sun A B
+ Author Affiliations
- Author Affiliations

A Key Laboratory of Inorganic Molecule-Based Chemistry of Liaoning Province, Shenyang University of Chemical Technology, Shenyang 110142, China.

B Corresponding authors. Email: youlx@syuct.edu.cn; sunyaguang@syuct.edu.cn

Australian Journal of Chemistry 73(1) 16-20 https://doi.org/10.1071/CH19314
Submitted: 10 July 2019  Accepted: 23 October 2019   Published: 10 December 2019

Abstract

Three new coordination polymers, {[Ln(cbb)(Hcbb)(DMF)·H2O]n, Ln = Sm (1), Eu (2), Tb(3), H2cbb = 2-(4-carboxybenzyloxy) benzoic acid, DMF = N,N-dimethylformamide}, have been synthesised by a solvothermal reaction and structurally characterised by infrared spectroscopy, elemental analysis, thermogravimetry analysis, and X-ray single-crystal diffraction. The results of single-crystal X-ray diffraction indicate that the coordination polymers 1–3 are isostructural, belong to a triclinic system, space group P-1, and show 1D chain structures through the H2cbb ligands connecting adjacent lanthanide ions. In addition, the fluorescence properties of polymers 1–3 were also investigated.


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