Contrasting Reactivity of 2-Mesityl-1,8-Naphthyridine (Mes-NP) with Singly-Bonded [RhII–RhII] and [RuI–RuI] Compounds

Biswajit Saha; S. M. Wahidur Rahaman; Arup Sinha; Jitendra K. Bera

doi:10.1071/CH11060

RESEARCH FRONT

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Contrasting Reactivity of 2-Mesityl-1,8-Naphthyridine (Mes-NP) with Singly-Bonded [Rh^II–Rh^II] and [Ru^I–Ru^I] Compounds

Biswajit Saha ^A , S. M. Wahidur Rahaman ^A , Arup Sinha ^A and Jitendra K. Bera ^A ^B

+ Author Affiliations

- Author Affiliations

^A Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India.

^B Corresponding author. Email: jbera@iitk.ac.in

Australian Journal of Chemistry 64(5) 583-589 https://doi.org/10.1071/CH11060
Submitted: 3 February 2011 Accepted: 12 April 2011 Published: 30 May 2011

Abstract

Reaction of cis-[Rh₂(CH₃COO)₂(CH₃CN)₆](BF₄)₂ with two equivalents of 2-mesityl-1,8-naphthyridine (Mes-NP) affords trans-[Rh₂(CH₃COO)₂(Mes-NP)₂](BF₄)₂ (1). X-ray structure reveals weak Rh–C(ipso) interaction, and a short Rh–Rh distance. The same ligand, in contrast, oxidatively cleaves the Ru–Ru bond in cis-[Ru₂(CO)₄(CH₃CN)₆](BF₄)₂ and results in trans-[Ru(Mes-NP)₂(CH₃CN)₂](BF₄)₂ (2). Both compounds adopt trans geometry to relieve the steric strain. Compound 2 exhibits moderate activity for the alcohol oxidation and aldehyde olefination reactions.

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Contrasting Reactivity of 2-Mesityl-1,8-Naphthyridine (Mes-NP) with Singly-Bonded [RhII–RhII] and [RuI–RuI] Compounds

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Contrasting Reactivity of 2-Mesityl-1,8-Naphthyridine (Mes-NP) with Singly-Bonded [Rh^II–Rh^II] and [Ru^I–Ru^I] Compounds