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Environmental problems - Chemical approaches
Environmental Chemistry

Environmental Chemistry

Volume 15 Number 7 2018

EN18073Arsenic concentrations and speciation in Australian and imported rice and commercial rice products

William Maher 0000-0001-7564-3383, Elliott Duncan, Hayden Martin, Peter Snell, Frank Krikowa, Rajani Jagtap, Simon Foster, Tariq Ezaz 0000-0003-4763-1347 and Michael J. Ellwood
pp. 387-402

Environmental context. In countries where inhabitants are not exposed to arsenic-contaminated drinking water, food is the major source of potentially toxic inorganic arsenic. To complement the existing worldwide dataset on arsenic in rice, data are presented on Australian- and overseas-grown rice, and assessed in terms of possible risk. Only a diet comprising multiple serves of some rice products per day poses a potential risk to young children.

EN18072Mobile-phone-based colourimetric analysis for determining nitrite content in water

Chanida Puangpila 0000-0002-6817-8791, Jaroon Jakmunee, Somkid Pencharee and Wipada Pensrisirikul
pp. 403-410

Environmental context. A widespread pollutant in groundwater, rivers and lakes is nitrite, which is commonly determined batchwise by using colourimetry. The batchwise method, however, requires relatively large and expensive instrumentation, and hence is unsuitable for in-field measurements. This work introduces a simple and portable colourimetric analyser based on a mobile-phone camera for monitoring nitrite concentrations in environmental water samples.


Environmental context. Acetate esters, emitted into the atmosphere from both natural and anthropogenic sources, can participate in photochemical processes leading to the formation of secondary organic aerosols. We report a study on the kinetics and mechanisms of the reaction of two acetate esters with O3, OH, NO3, and Cl radicals. The results help our understanding of the chemical behaviour of this important class of compounds in the atmosphere.


Environmental context. Global warming is an important problem for life on Earth, and there is an increasing need to understand how organisms respond to rising temperatures. We show that an Antarctic fish, the emerald rockcod, can acclimate to thermal shock by modifying the fatty acid composition and total lipid content in its gills. This study contributes to our understanding of how the physiology of Antarctic life could be influenced by climate change.

EN18108Measuring dissolved organic matter in estuarine and marine waters: size-exclusion chromatography with various detection methods

Gabriel Dulaquais 0000-0001-9110-0469, Johann Breitenstein, Matthieu Waeles, Rémi Marsac and Ricardo Riso
pp. 436-449

Environmental context. Dissolved organic matter (DOM), a key parameter in aquatic biogeochemistry, is difficult to characterise owing to its variable composition and structure. We report a chromatographic method with carbon, nitrogen and absorbance detection able to record the size distribution of DOM and changes in its composition. The method could be used to identify additional sources to river or coastal waters as well as monitoring the DOM size/reactivity continuum in open oceans.

EN18056Aging of silver nanocolloids in sunlight: particle size has a major influence

Sylvie Motellier 0000-0003-0490-8430, Nathalie Pélissier and Jean-Gabriel Mattei
pp. 450-462

Environmental context. Transformation of silver nanoparticles in the environment is an important issue because the form they take directly influences what effect they have. We show that the size of the primary particles of silver nanosuspensions is a major factor determining their evolution under sunlight irradiation (dissolution, formation of nanoseeds and nanoprisms, agglomeration). The persistence of nano-sized silver particles after exposure to sunlight irradiation implies that their ecotoxicological impact will likely last well beyond their introduction in the environment.

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