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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Australian Journal of Chemistry

Australian Journal of Chemistry

Volume 74 Number 2 2021

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This review article highlights the state of the art in solid-state SEC (ultraviolet–visible–near-infrared (UV-Vis-NIR), infrared (IR), Raman, photoluminescence, electron paramagnetic resonance (EPR), and X-ray absorption (XAS) spectroscopy) relevant to interrogating solid-state materials, particularly those in the burgeoning field of metal–organic frameworks (MOFs).

CH19668New Bidentate N-Sulfonyl-Substituted Aromatic Amines as Chelate Ligand Backbones: Pd Catalyst Generation in C–C Coupling via In Situ and Precatalyst Modes

Hammed Olawale Oloyede, Raymond Akong Akong, Joseph Anthony Orighomisan Woods, Helmar Görls, Winfried Plass 0000-0003-3473-9682 and Abiodun Omokehinde Eseola 0000-0003-4713-2468
pp. 101-110
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Six structurally diverse sulphonamide-based ligands and monodentate N-donor co-ligands were used to obtain new palladium(II) complexes, which have been used to study C–C coupling catalysis. It was concluded that coordinative saturation is undesirable and that steric repulsion between the synthesised ligands and the bulkier co-ligands aided the generation of vacant coordination sites for the more active complexes.

CH20109Some Products from C=O Condensations of Quinacridones

Anthony S. R. Chesman 0000-0002-1807-4468 and Andris J. Liepa
pp. 111-124
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Functionalised quinacridones can act as both pigments and n-type materials in optoelectronic devices. To date, approaches to structural modifications have been limited in scope. An alternative route to selectively activating quinacridone carbonyl groups provides a means for accessing a diverse library of substituted quinacridone derivatives.

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A new temozolomide (TMZ) formulation for local chemotherapy of glioblastoma was prepared by incorporating TMZ-loaded solid lipid nanoparticles into MRI-visible injectable hydrogel of hydroxypropyl chitosan/diaryaldehyde PEG. The good drug-loading capacity, retarded release and in situ gelation of the hydrogel facilitate the compact filling of the operation cavity and sustained release of TMZ.

CH20099CO2-Responsive Spherical Polyelectrolyte Brush with Multi-Stimulation for Reversible Protein Immobilization and Release

Rui Zhang 0000-0003-1370-8289, Qionglong Fu, Di Zhu, Zheqi Shen, Keming Zhou, Yuan Yao and Xuedong Zhu
pp. 135-144
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Multi-responsive spherical polyelectrolyte brushes were adopted as a good absorbent for protein due to the Donna effect and electrostatic interactions. The adsorption and release process could be triggered by pH, ionic strength, temperature, or CO2/N2. For a gas trigger, salt accumulation was avoided even after many cycles.

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